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For music get the doubletwist app, for both the phone & your pc/mac, it's almost a clone of iTunes, & will automatically sync your iTunes playlists ready for use on the desire,Sounds good, that's the one thing now, I've got my music organised how I like it on Itunes (which I'm still not a massive fan of) because of the iPhone.
With regards to the contacts etc transferring from Iphone to Desire I'm assuming you've had to do this back and forth yourself.
I've set my googlemail up last month to sync the Iphone to that, but never did it as I was ill at the time and the sync seemed to imply it was going to do it the wrong way around (ie empty google to my iphone) and then just forgot all about it.
I'm assuming I should be able to sync Iphone to that and then sync google to the Desire? Is that the best option, I'm assuming it will be.
www.last.fm/user/1mills
For your contacts, use sync in a blink from the app store, it's 59p iirc, & it'll sync all your google contacts back & forth between the iPhone & google, then they will appear on the desire next time you sign into google via the phone
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Forever <M.A.D>
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Cheers, I'll do the swap over tonight and then give it a blast for a week and see how I get on with it 
www.last.fm/user/1mills